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南开2019年代表性论文Small [复制链接]

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发表于 2019-5-4 13:57:31 来自手机 |显示全部楼层
本帖最后由 NKU 于 2019-5-4 16:51 编辑

元素有机化学研究所周其林课题组朱守非教授ACS Catalysis,通讯作者:朱守非
ACS Catal., Just Accepted Publication Date (Web): May 3, 2019 (Letter) DOI: 10.1021/acscatal.9b01187
https://pubs.acs.org/doi/pdf/10.1021/acscatal.9b01187


Rhodium-Catalyzed Si–H Bond Insertion Reactions Using Functionalized Alkynes as Carbene Precursors

Ming-Yao Huang,§ Ji-Min Yang,§ Yu-Tao Zhao, Shou-Fei Zhu*

State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

* sfzhu nankai edu cn

§ M.-Y. Huang and J.-M. Yang contributed equally to this work.


ABSTRACT: Enantioselective transition-metal-catalyzed carbene insertion into Si–H bonds is a promising method for preparing chiral organosilicons; however, all the carbene precursors used to date in this reaction ha ve been diazo compounds, which significantly limits the structural diversity of the resulting chiral organosilicons. Herein, we report a protocol for rhodium-catalyzed asymmetric Si–H bond insertion reactions that use functionalized alkynes as carbene precursors. With chiral dirhodium tetracarboxylates as catalysts, the reactions of carbonyl-ene-ynes and silanes smoothly ga ve chiral organosilanes in high yields (up to 98%) with excellent enantioselectivity (up to 98% ee). Kinetic studies suggest that insertion of the in situ generated rhodium carbenes into the Si–H bonds of the silanes is probably the rate-determining step. This work represents the first enantioselective Si–H bond insertion reaction using alkynes as carbene precursors and opens the door for preparing chiral organosilicons with unprecedented structural diversity from readily a vailable alkynes.

KEYWORDS: Asymmetric synthesis, chiral organosilicons, rhodium carbenes, Si–H bond insertion, alkynes

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发表于 2019-5-4 14:29:03 来自手机 |显示全部楼层
本帖最后由 南以离开 于 2019-5-4 14:31 编辑

发一个关于高招的吧~招办主任说今年还会扩招
今年南开大学将外国语言文学类专业的招生批次调整为提前批,这样很多喜欢语言文学的考生,尤其是文科考生就可以提前报考,等于是在报考志愿方面让学生又多了一次机会。

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发表于 2019-5-7 06:14:55 |显示全部楼层
本帖最后由 NKU 于 2019-5-7 06:18 编辑

化学学院张振杰研究员ANGEWANDTE,通讯作者:张振杰、Banglin Chen、Libo Li
Angew. Chem. Int. Ed., DOI:10.1002/anie.201904312, First published: 06 May 2019
https://onlinelibrary.wiley.com/doi/10.1002/anie.201904312

Robust Microporous Metal-Organic Frameworks for Highly Efficient and Simultaneous Removal of Propyne and Propadiene
from Propylene
Yun-Lei Peng,# [a] Chaohui He,# [c] Tony Pham,[g] Ting Wang,[a] Pengfei Li,[e] Rajamani Krishna,Katherine
A. Forrest,[g ] Adam Hogan,[g] Shanelle Suepaul,[g] Brian Space,[g] Ming Fang,[e] Yao Chen,[f] Michael J. Zaworotko,[h] Jinping Li,[c] Libo Li,* [b ], [c] Zhenjie Zhang,* [a], [d], [f] Peng Cheng,[a], [d]Banglin Chen* [b ]

[a] Y.-L. Peng, T. Wang, Prof. P. Cheng, Prof. Z. Zhang
College of Chemistry, Nankai University, Tianjin, 300071, P. R. China E-mail: zhangzhenjie nankai.edu.cn
[b ] Prof. L. Li, Prof. B. Chen
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, United States E-mail: banglin.chen utsa.edu
[c] C. He, Prof. J. Li, Prof. L. Li
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, 030024, Shanxi, P. R. China E-mail: lilibo908 hotmail.com,
[d] Prof. P. Cheng, Prof. Z. Zhang
Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin 300071, P. R. China
[e] P. Li, M. Fang
Department of Chemistry, Hebei Normal University of Science & Technology, Qinhuangdao, 066004, Hebei, China
[f] Prof. Y. Chen, Prof. Z. Zhang
State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, P. R. China.
[g] T. Pham, K. A. Forrest, A. Hogan, S. Suepaul, Prof. B. Space
Department of Chemistry, University of South Florida, 4202 East Fowler A venue, CHE205, Tampa, Florida 33620-5250, United States.
[h] Prof. M. J. Zaworotko
Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick V94T9PX, Republic of Ireland.
Prof. R. Krishna
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands.
[#] These authors contributed equally to this work.

Abstract

Simultaneous removal of trace amount of propyne and propadiene from propylene is an important but challenging industrial process. In this study, we reported a class of microporous metal‐organic frameworks (NKMOF‐1‐M) with exceptional water stability and remarkably high uptakes for both propyne and propadiene at low pressures. Attributed to the strong bind affinity to propyne and propadiene over propylene, NKMOF‐1‐M created new benchmark selectivities for ternary propyne/propadiene/propylene (0.5/0.5/99.0) mixture, and set as a unique MOF platform to achieve both the highest selectivity and productivity of polymer‐grade propylene (99.996%) at ambient temperature, verified by both simulated and experimental breakthrough results. Moreover, we demonstrated a rare example to visualize propyne and propadiene molecules in the single‐crystal structure of NKMOF‐1‐M through a convenient approach under ambient condition, which helped to precisely understand the binding sites and affinity of propyne and propadiene. These results provide important guidance on using ultramicroporous MOFs as physisorbent materials to resolve industrial challenges related to ternary propyne/propadiene/propylene mixture separation.

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发表于 2019-5-7 10:12:10 |显示全部楼层
5月6日,天津市科协常务副主席陆为民、副主席白景美一行访问南开大学。校长曹雪涛在津南校区综合业务东楼会见了客人。双方围绕全域科普、院士增选、科技创新、人才工作等内容进行深入交流。

希望今年能新增院士

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发表于 2019-5-7 18:49:25 |显示全部楼层
《中国科学: 化学》(英文刊)南开专辑
SPECIAL ISSUE: Dedicated to the 100th Anniversary of Nankai University
http://engine.scichina.com/publisher/scp/journal/SCC/62/5?slug=browse
https://link.springer.com/content/pdf/10.1007%2Fs11426-019-9476-8.pdf

汤平平 SCIENCE CHINA Chemistry 62(5), 525-532 (2019)  https://doi.org/10.1007/s11426-018-9402-x
陈军 SCIENCE CHINA Chemistry 62(5), 533-548 (2019)  https://doi.org/10.1007/s11426-018-9410-0
刘育 SCIENCE CHINA Chemistry 62(5), 549-560 (2019)  https://doi.org/10.1007/s11426-018-9405-3
周传政 SCIENCE CHINA Chemistry 62(5), 561-570 (2019)  https://doi.org/10.1007/s11426-018-9421-5
崔春明,李建峰 SCIENCE CHINA Chemistry 62(5), 571-582 (2019)  https://doi.org/10.1007/s11426-018-9403-7
邵学广 SCIENCE CHINA Chemistry 62(5), 583-591 (2019)  https://doi.org/10.1007/s11426-018-9398-2
陈弓,何刚 SCIENCE CHINA Chemistry 62(5), 592-596 (2019)  https://doi.org/10.1007/s11426-018-9409-3
张弛 SCIENCE CHINA Chemistry 62(5), 597-601 (2019)  https://doi.org/10.1007/s11426-018-9400-2
程鹏,师唯 SCIENCE CHINA Chemistry 62(5), 602-608 (2019)  https://doi.org/10.1007/s11426-018-9370-0
牛志强 SCIENCE CHINA Chemistry 62(5), 609-615 (2019)  https://doi.org/10.1007/s11426-018-9394-1
李福军 SCIENCE CHINA Chemistry 62(5), 616-621 (2019)  https://doi.org/10.1007/s11426-018-9422-y
赵斌 SCIENCE CHINA Chemistry 62(5), 622-628 (2019)  https://doi.org/10.1007/s11426-018-9420-6
袁明鉴 SCIENCE CHINA Chemistry 62(5), 629-636 (2019)  https://doi.org/10.1007/s11426-018-9436-1
史林启,马如江 SCIENCE CHINA Chemistry 62(5), 637-648 (2019)  https://doi.org/10.1007/s11426-018-9419-3
李鑫 SCIENCE CHINA Chemistry 62(5), 649-652 (2019)  https://doi.org/10.1007/s11426-018-9393-2

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发表于 2019-5-7 22:42:35 |显示全部楼层
化学学院师唯教授Chem,通讯作者:师唯,Michael J. Zaworotko
Chem, In press, corrected proof, A vailable online 6 May 2019, 10.1016/j.chempr.2019.04.010
https://www.sciencedirect.com/science/article/pii/S2451929419301688

A Gadolinium(III) Zeolite-like Metal-Organic-Framework-Based Magnetic Resonance Thermometer
Shi-Yuan Zhang 12, Zhong-Yan Wang 3, Jie Gao 4, Kunyu Wang 1, Eliana Gianolio 5, Silvio Aime 5, Wei Shi 1*, Zhen Zhou 6, Peng Cheng 1, Michael J. Zaworotko 27*

1Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China
2Department of Chemical Science, Bernal Institute, University of Limerick, Limerick, Republic of Ireland
3Tianjin Key Laboratory of Radiation Medicine and Molecular Nuclear Medicine, Institute of Radiation Medicine, Chinese Academy of Medical Sciences & Peking Union Medical College, Tianjin 300192, China
4State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, China
5Centro di Biotechnologie Molecolari, University of Torino, Torino 10125, Italy
6School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Nankai University, Tianjin 300350, China

*shiwei nankai.edu.cn

*xtal ul.ie

Summary

MRI contrast agents (CAs) feature coordinated water molecule(s) (aqua ligands), which renders them unsuitable for magnetic resonance (MR) temperature mapping because of their resulting sensitivity to metabolic and physiological changes and/or their tendency to release toxic Gd3+ cations. Herein, we introduce an approach to temperature mapping based upon a coordinatively saturated gadolinium (Gd)-based metal-organic framework (MOF) that exhibits enhanced proton relaxation and high temperature sensitivity. The stable, non-toxic Gd zeolite-like MOF Gd-ZMOF was observed to generate a large enhancement in contrast as a result of a large (70%) contribution from second-sphere water relaxivity. Temperature mapping by clinical CAs and Gd-ZMOF by means of longitudinal (T1) relaxivity was investigated. Gd-ZMOF enabled the visualization of small temperature changes, especially in the thermal therapy region (41°C–45°C). In vivo thermal imaging demonstrates the feasibility of Gd-ZMOF as an MR thermometer and as a potential theranostic.

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发表于 2019-5-7 23:18:20 来自手机 |显示全部楼层
本帖最后由 NKU 于 2019-5-8 07:14 编辑

@woaitjdaa,论文里南开的百年校庆祝福语比较单调,基本都是dedicated to the 100th anniversary of Nankai University,celebrate Nankai University’s centennial birthday,有几篇是说庆祝刘育教授、廖代正教授等生日。好像没有说感谢所有教师和校友的。

化学院包含的环境化学、生物化学、药物化学、材料化学这二十年来基本都独立成实体学院(研究所),目前主要剩余有机化学、无机化学、高分子化学、分析化学、物理化学、化学生物学、植物病理学、农业昆虫与害虫防治,农药学、精细化学品化学

南开化学院可以把植物保护(植物病理学、农业昆虫与害虫防治、农药学)独立出来,成立现代农学院(这名字可能不好招生),这样化学院规模会小一点。当然不是做简单的拆分,还是希望每个学科做大一点,指标好看一点。不过我想学校目前主要精力在于扶持新分出来的材料化学(材料学院),但是速度还是太慢。

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发表于 2019-5-8 19:27:49 |显示全部楼层
应该不会,ESI南开农业科学是退步最快的学科之一,南开也只有农药学一个二级学科而已。

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发表于 2019-5-10 22:15:30 |显示全部楼层
环境科学与工程学院展思辉教授ADVANCED MATERIALS,通讯作者:展思辉
ADVANCED MATERIALS, DOI:10.1002/adma.201806843, First published: 10 May 2019
https://onlinelibrary.wiley.com/doi/10.1002/adma.201806843

3D Graphene-Based Macrostructures for Water Treatment
Haitao Wang, Xueyue Mi, Yi Li, and Sihui Zhan*


Abstract

Recently, 3D graphene‐based macrostructures (3D GBMs) ha ve gained increased attention due to their immense application potential in water treatment. The unique structural features (e.g., large surface area and physically interconnected porous network) as well as fascinating properties (e.g., high electrical conductivity, excellent chemical/thermal stability, ultralightness, and high solar‐to‐thermal conversion efficiency) render 3D GBMs as promising materials for water purification through adsorption, capacitive deionization, and solar distillation. Moreover, 3D GBMs can serve as scaffolds to immobilize powder nanomaterials to build monolithic adsorbents and photo‐/electrocatalysts, which significantly broadens their potential applications in water treatment. Here, recent advances in their synthesis and application toward water purification are highlighted. Remaining challenges and future perspectives are elaborated to highlight future research directions.

Prof. H. Wang, Dr. X. Mi, Prof. S. Zhan
Key Laboratory of Pollution Processes and Environmental Criteria (Ministry of Education), Tianjin Key Lab for Rare Earth Materials and Applications, School of Environmental Science and Engineering, Nankai University, Tianjin 300350, P. R. China
E-mail: sihuizhan nankai.edu.cn
Prof. Y. Li
Department of Chemistry, Tianjin University, Tianjin 300072, P. R. China

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发表于 2019-5-11 09:38:12 |显示全部楼层
@woaitjdaa

这十年南开进步速度真是慢了很多。
2019年1月南开ESI情况见http://bbs1.netbig.com/thread-2962869-1-1.html

2019年3月南开ESI情况见http://bbs1.netbig.com/thread-2958227-5-1.html  148楼

2019年5月南开ESI情况如下:

平均引用
除了数学、植物学小于10以外,其他学科均大于10,唯一平均引用超过16的大陆高校,高校篇均第一。其中化学平均引用为20.34、材料为27.49、分子生物与遗传学22.71。

总引方面
化学全球排名40,位于芝加哥大学后面,牛津大学、复旦大学前面,比三月-1
数学全球排名81,位于香港中文大学后面,比三月+3
材料全球排名103,位于牛津大学后面,香港科技大学前面,比三月持平

其他没有进前100的

Indicators Results List: ResearchFields   Filter Results By: Institutions   Filter Value(s): NANKAI UNIVERSITY   Show: Top
Research Fields
Web of Science Documents
Cites
Cites/Paper
Top Papers
1
CHEMISTRY
8069
164153
20.34
175
2
MATERIALS SCIENCE
2081
57207
27.49
100
3
PHYSICS
3236
39867
12.32
74
4
ENVIRONMENT/ECOLOGY
1027
17392
16.93
18
5
BIOLOGY & BIOCHEMISTRY
1205
16757
13.91
8
6
MOLECULAR BIOLOGY & GENETICS
648
14713
22.71
4
7
ENGINEERING
1207
13246
10.97
26
8
CLINICAL MEDICINE
793
9007
11.36
4
9
MATHEMATICS
1635
8039
4.92
28
10
PHARMACOLOGY & TOXICOLOGY
428
6346
14.83
5
11
AGRICULTURAL SCIENCES
258
3616
14.02
1
12
PLANT & ANIMAL SCIENCE
579
2825
4.88
3
ALL FIELDS
22834
369851
16.2
477
Copyright ?2019 Clarivate Analytics


Incites情况
2019年5月(更新至4月30),农业科学、植物学、微生物学都有不同程度下降,按道理计算机科学可以进入了。
                                                                           
学科                              文章数     被引次数                          
Computer science            370           3375                            
econonics&business         311           2177                              
geoscience                       94           1191                              
Immunology                    146          2252                              
Microbiology                    318          4329                                
Mutidisciplinary                 19           351                                 
Neuroscience&beha-vior     192         2160                          
Plant&animal science         581         2966                        
Psychiatry&Psychology       48            835                              
Social Science,General    159          1222                          
Space Science                  37            349

2019年五月检索阈值

THRESHOLD-ESI

RESEARCH FIELDS

AUTHOR

INSTITUTION

JOURNAL

COUNTRY

AGRICULTURAL SCIENCES

439

2129

1851

1016

BIOLOGY & BIOCHEMISTRY

910

6147

7068

865

CHEMISTRY

1865

7826

6234

1689

CLINICAL MEDICINE

2022

2530

5022

9923

COMPUTER SCIENCE

369

3212

1427

417

ECONOMICS & BUSINESS

372

4037

1378

231

ENGINEERING

605

2494

2564

1131

ENVIRONMENT/ECOLOGY

783

4047

3222

2179

GEOSCIENCES

1169

6006

2630

1175

IMMUNOLOGY

909

4848

7647

2139

MATERIALS SCIENCE

1655

6098

2683

1136

MATHEMATICS

312

4087

1484

396

MICROBIOLOGY

669

5093

3519

1256

MOLECULAR BIOLOGY & GENETICS

2442

13520

6913

1841

MULTIDISCIPLINARY

571

2621

113

204

NEUROSCIENCE & BEHA VIOR

1230

6206

7919

559

PHARMACOLOGY & TOXICOLOGY

534

3343

5305

854

PHYSICS

10956

19763

4414

1717

PLANT & ANIMAL SCIENCE

609

2821

2315

1715

PSYCHIATRY/PSYCHOLOGY

729

3880

2539

298

SOCIAL SCIENCES, GENERAL

366

1418

1001

1254

SPACE SCIENCE

5533

38106

1452

746

Copyright 2019 Clarivate Analytics


                        



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发表于 2019-5-11 12:44:21 来自手机 |显示全部楼层
连续被华南理工 苏大超越  
南开越难越来

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发表于 2019-5-12 13:00:56 |显示全部楼层
金融学院贺佳助理教授金融学顶级期刊Journal of Financial Economics
贺佳很强,好些篇顶级期刊,不过这篇不是一作或通讯

Do Real Estate Agents Ha ve Information Advantages in Housing Markets?
Journal of Financial Economics, In press, accepted manuscript, A vailable online 10 May 2019, 10.1016/j.jfineco.2019.05.008
Sumit Agarwal, Jia He, Tien Foo Sing, Changcheng Song
https://www.sciencedirect.com/science/article/pii/S0304405X19301229

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发表于 2019-5-12 13:03:01 来自手机 |显示全部楼层
woaitjdaa 发表于 2019-5-12 13:00
金融学院贺佳助理教授金融学顶级期刊Journal of Financial Economics
贺佳很强,好些篇顶级期刊,不过这篇 ...

小心跑了 不仅是去其他大学 还有可能去金融机构的研究部门

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发表于 2019-5-12 14:03:20 |显示全部楼层
本帖最后由 woaitjdaa 于 2019-5-12 14:14 编辑

我觉得走很正常,国内外商学院教授的工资待遇差别太大了,金融学院走了好几个了(算上接收没来)。
美国很差的公立大学商学院助理教授一般有30万美元年薪(9个月)左右,国内怎么和别人比。

美国大学理科,工科,人文,社科相对工资低,招这些方面的回来还可能。不过人文,社科不支撑数据,国内高校一般不感兴趣。
好的公立大学工科assistant professor正常也就8万左右,理科少个1万来美元,人文社科低的可能也只有4-5万。理科和工科暑假3个月还有科研经费配给自己,人文社科教授暑假都没钱发给自己。

所以理工科的青千回国很划算,国内还可以兼职赚钱。之前看到在国内宣传比较多的有名国外正教授,在加州大学某分校网上显示年薪也就11万。
在美国理工科教授科研和教学的负担很重,尤其是没拿到tenure前的助理教授。除了computer science的教授在外创业或兼职的不少,其他专业很难要看有没有机缘,或是外面真的需要。

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发表于 2019-5-12 14:08:20 来自手机 |显示全部楼层
woaitjdaa 发表于 2019-5-12 14:03
我觉得走很正常,国内外商学院教授的工资待遇差别太大了,金融学院走了好几个了(算上接收没来)。
美国很 ...

商学院30万 文科5万 能差六倍么……

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发表于 2019-5-12 14:17:47 |显示全部楼层
本帖最后由 woaitjdaa 于 2019-5-12 14:23 编辑
nkuthu1 发表于 2019-5-12 14:08
商学院30万 文科5万 能差六倍么……


可能有些夸张吧,但商学院低的助理教授也有20多万,相同档次,在本学科相同地位,助理教授能相差到那么大,研究型大学我还看到过有3万多美元的呢。美国商学院,法学院,医学院工资都高的离谱。医学院资深点的research assistant peofessor都能超过10万,依赖于大老板,比一些生物系的正教授可能都高。

公立大学理工科有名的冠名教授看级别,一般也就20万,30万两个级别,当然牛的谁都不知道工资多少。

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发表于 2019-5-12 14:34:20 来自手机 |显示全部楼层
woaitjdaa 发表于 2019-5-12 14:17
可能有些夸张吧,但商学院低的助理教授也有20多万,相同档次,在本学科相同地位,助理教授能相差到那么大 ...

那很高了 phd入职高盛美国第一年大概率不会超过12万刀…含奖金

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发表于 2019-5-14 07:40:13 |显示全部楼层
材料科学与工程学院卜显和课题组Nano Energy,通讯作者:王丹红,卜显和
Nano Energy, In press, accepted manuscript, A vailable online 13 May 2019, 10.1016/j.nanoen.2019.05.030
https://www.sciencedirect.com/science/article/pii/S2211285519304367

Nitrogen-doped carbon shell-confined Ni3S2 composite nanosheets derived from Ni-MOF for high performance sodium-ion battery anodes
Wei Shuang a, Hui Huang a, Lingjun Kong a, Ming Zhong a, Ang Lia, Danhong Wang a*, Yunhua Xu d, Xian-He Bu abc*
a School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin, 300350, PR China
b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, 300072, PR China
c Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, PR China
d School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), and Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin, 300072, China
*Corresponding author.

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发表于 2019-5-14 19:19:00 |显示全部楼层
元素所崔春明教授通讯作者ANGEWANDTE
Angew. Chem. Int. Ed., DOI:10.1002/anie.201903418, First published: 14 May 2019
https://www.onlinelibrary.wiley.com/doi/10.1002/anie.201903418

Regioselective Functionalization of Stable BN-embedded Luminescent Tetraphenes for High-Resolution Fingerprint Imaging
Huanan Huang*[a], Ying Zhou[a], Meng Wang[c], Jianying Zhang[b ], Xiaohua Cao[a], Shitao Wang[c],
Dapeng Cao*[a, c], Chunming Cui*[b ]

[a] Dr. H.-N. Huang, Y. Zhou, Prof. X.-H. Cao, Prof. D. P. Cao
School of Chemistry and Environmental Engineering; Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang University, Jiujiang 332005, China  E-mail:huanan200890 163.com
[b ] Prof. C.-M. Cui, J.-Y. Zhang.
State Key Laboratory of Elemento-Organic Chemistry; Cooperative Innovation Center of Chemical Science and Engineering (Tianjin) Nankai University, Tianjin 300071, China E-mail: cmcui nankai.edu.cn
[c] M. Wang, Dr. S.-T. Wang, Prof. D .P. Cao
State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, China E-mail: caodp mail.buct.edu.cn

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发表于 2019-5-14 19:27:45 |显示全部楼层
南开碉堡,祝贺!

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发表于 2019-5-14 19:42:40 来自手机 |显示全部楼层
maicon08 发表于 2019-5-14 19:27
南开碉堡,祝贺!

谢谢!!还有很大差距…

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发表于 2019-5-14 21:22:05 来自手机 |显示全部楼层
再接再厉  加油

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发表于 2019-5-15 23:36:19 |显示全部楼层
化学学院高分子所张会旗教授ADVANCED MATERIALS,通讯作者:张会旗
ADVANCED MATERIALS, DOI:10.1002/adma.201806328, First published: 15 May 2019
https://onlinelibrary.wiley.com/doi/10.1002/adma.201806328

Molecularly Imprinted Nanoparticles for Biomedical Applications
Huiqi Zhang

Prof. H. Zhang
State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Functional Polymer Materials (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), College of Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: zhanghuiqi nankai edu cn

Abstract

Molecularly imprinted polymers (MIPs) are synthetic receptors with tailor‐made recognition sites for target molecules. Their high affinity and selectivity, excellent stability, easy preparation, and low cost make them promising substitutes to biological receptors in many applications where molecular recognition is important. In particular, spherical MIP nanoparticles (or nanoMIPs) with diameters typically below 200 nm ha ve drawn great attention because of their high surface‐area‐to‐volume ratio, easy removal of templates, rapid binding kinetics, good dispersion and handling ability, undemanding functionalization and surface modification, and their high compatibility with various nanodevices and in vivo biomedical applications. Recent years ha ve witnessed significant progress made in the preparation of advanced functional nanoMIPs, which has eventually led to the rapid expansion of the MIP applications from the traditional separation and catalysis fields to the burgeoning biomedical areas. Here, a comprehensive overview of key recent advances made in the preparation of nanoMIPs and their important biomedical applications (including immunoassays, drug delivery, bioimaging, and biomimetic nanomedicine) is presented. The pros and cons of each synthetic strategy for nanoMIPs and their biomedical applications are discussed and the present challenges and future perspectives of the biomedical applications of nanoMIPs are also highlighted.

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发表于 2019-5-15 23:39:52 |显示全部楼层
材料科学与工程学院卜显和课题组ANGEWANDTE,通讯作者:卜显和教授
Angew. Chem. Int. Ed., DOI:10.1002/anie.201903817, First published: 15 May 2019
https://onlinelibrary.wiley.com/doi/10.1002/anie.201903817

A Giant Dy76 Cluster: A New Fused Bi-Nanopillar Structural Model in Lanthanide Clusters
Xiao-Yu Li,[a] Hai-Feng Su,[d] Quan-Wen Li,[b,c] Rui Feng,[b ] Hui-Yun Bai,[b ] Hua-Yu Chen,[b ] Jian Xu,[a] and Xian-He Bu*[a,b,c]

[a] X.-Y. Li, Dr. J. Xu, Prof. X.-H. Bu
School of Materials Science and Engineering, National Institute for Advanced Materials, Tianjin Key Laboratory of Metal and
Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, P. R. China.
E-mail: buxh nankai.edu.cn
Dr. Q.-W. Li, R. Feng, H.-Y. Bai, H.-Y. Chen, Prof. X.-H. Bu
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China.
[c] Dr. Q.-W. Li, Prof. X.-H. Bu
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China.
[d] Prof. H.-F. Su
State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical
Engineering, Xiamen University, Xiamen 361005, P. R. China.

Abstract

Although great achievements ha ve been made in the synthesis of giant lanthanide clusters, the novel structure models are still scanty. Here, we report a giant lanthanide cluster Dy₇₆ constructed by [Dy₃(μ₃‐OH)₄] and [Dy₅(μ₄‐O)(μ₃‐OH)₈] building blocks. As the largest known Dy cluster, the structure of Dy₇₆ can be seen as arising from the fusion of two Dy₄₈ clusters and they can be isolated under various synthetic conditions and characterized by single‐crystal X‐ray diffraction. Such a new fused structural model of pillar motif has not been found in Ln clusters. Furthermore, the successful conversion from Dy₇₆ back to Dy₄₈ in a retrosynthetic manner supports the proposed fused formation mechanism of Dy₇₆. Electrospray ionization mass spectrometry (ESI‐MS) analysis suggests that the metal cluster skeleton of Dy₇₆ has good stability in various solvents. This work not only reveals a new structural type of Ln clusters but also gives a deep insight about the novel fusion assembly process.

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发表于 2019-5-16 09:42:49 来自手机 |显示全部楼层
卜显和今年论文可以啊

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发表于 2019-5-16 19:38:58 |显示全部楼层
本帖最后由 NKU 于 2019-5-16 19:46 编辑

以下转自我爱南开bbs

卜显和教授今年已发表论文:

Angewandte Chemie International Edition Accepted Articles First published: 15 May 2019 10.1002/anie.201903817
Angewandte Chemie International Edition Volume 58, Issue 17, April 16, 2019, Pages 5614-5618, 10.1002/anie.201900190
Angewandte Chemie International Edition Volume 58, Issue 13, March 22, 2019, Pages 4339-4344, 10.1002/anie.201900789
Advanced Materials Early View First published: 18 March 2019 10.1002/adma.201806736
Coordination Chemistry Reviews, Volume 388, 1 June 2019, Pages 172-201
Coordination Chemistry Reviews, Volume 387, 15 May 2019, Pages 79-120
Coordination Chemistry Reviews, Volume 378, 1 January 2019, Pages 17-31
Nano Energy, In press, accepted manuscript, A vailable online 13 May 2019

Crystal Growth & Design, 2019, 19 (2), pp 1391–1398 (Article) DOI: 10.1021/acs.cgd.8b01791
Dalton Trans., 2019, 48, 387-394 10.1039/C8DT04230F
Inorg. Chem. Front., 2019, 6, 50-56 10.1039/C8QI00910D
Small Early View First published: 12 April 2019 10.1002/smll.201900426
Small Volume 15, Issue 3, January 18, 2019, 10.1002/smll.201804058

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发表于 2019-5-16 20:06:56 来自手机 |显示全部楼层
冲院士  加把劲

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发表于 2019-5-17 09:52:49 |显示全部楼层
1. 2019年南开大学电子信息与光学工程学院光学工程专业博士生指导教师郭雪峰(备注:系统中由向东老师代招);
http://eo.nankai.edu.cn/Recruitment/Detail?id=9090

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发表于 2019-5-17 22:55:10 |显示全部楼层
本帖最后由 NKU 于 2019-5-17 23:08 编辑

前几天还说南开化学类规模十名左右,现在连电子信息与光学工程学院都开始做化学和纳米了。

现代光学所的向东和北京大学化学院郭雪峰教授一直有合作,这几年南开开始招一点兼职博导了,所以郭不一定是全职的。郭雪峰做纳米的(隶属于北大物理化学学科)也是发了Science,总体上感觉纳米的发NS要相对容易些。

其实信息学科可以做一些类似于复旦大学ASIC国家重点实验室那样的方向,有利于学生的就业,接近工业界和产业界。学校现在做纳米好像也比其他高校晚了一点,不知道还能分到多少羹?

上次实验室评估把复旦的ASIC给整了一下,呵呵,这两年政府应该会重点投资这些领域吧,实用的工程领域,也许比一些没有尽头的基础和无法实现产业化的研究要迫切。国家钱多的话倒是无所谓,全面开花,钱没有那么多的情况下,还是做一些能改善民生的研究要好一些,杨振宁先生的话还是有点道理。

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发表于 2019-5-17 23:19:18 |显示全部楼层
南以离开 发表于 2019-5-17 09:52
1. 2019年南开大学电子信息与光学工程学院光学工程专业博士生指导教师郭雪峰(备注:系统中由向东老师代招 ...

http://www.chem.pku.edu.cn/szll/zzjs/wlhxyjs1/55902.htm

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